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            ASTM D1044透明塑料表面耐磨性試驗方法標(biāo)準(zhǔn)

            時間:2021/3/1閱讀:3541
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            4. Signifificance and Use
            4.1 Transparent plastic materials, when used as windows or
            enclosures, are subject to wiping and cleaning; hence the
            maintenance of optical quality of a material after abrasion is
            important. It is the purpose of this test method to provide a
            means of estimating the resistance of such materials to this type
            and degree of abrasion.



            4.2 Although this test method does not provide fundamental
            data, it is suitable for grading materials relative to this type of
            abrasion in a manner which correlates with service.
            4.3 Comparison of interlaboratory data or the specifification
            of a “haze” value has no signifificance if the hazemeter
            requirements given in 5.4 are not used. This is because light
            diffused from the surface of a Taber track is scattered at a
            narrow angle (Fig. 1 and Fig. 2) while light diffused internally
            by a specimen is scattered at a wide angle. In many hazemeters,
            when a diaphragm is inserted to limit the light beam to the
            width of the abraded track, the specular beam at the exit port
            becomes smaller. The dark annulus will then be greater than the
            0.023 6 0.002 rad (1.3 6 0.1°) requirements of Test Method
            D 1003. Since a large percentage of the narrow-angle forward
            scattered light will not impinge on the sphere wall, “haze”
            readings become smaller. For hazemeters that have not been
            properly adjusted, the magnitude of this reduction is dependent
            both on the integrating sphere diameter and the reduction of the
            entrance beam.
            4.4 For many materials, there may be a specifification that
            requires the use of this test method, but with some procedural
            modififications that take precedence when adhering to the
            specifification. Therefore, it is advisable to refer to that material
            specifification before using this test method. Table 1 of Classi-
            fification System D 4000 lists the ASTM materials standards that
            currently exist.
            4.5 For some materials, abrasion tests utilizing the Taber
            abraser may be subject to variation due to changes in the
            abrasive characteristics of the wheel during testing.
            4.5.1 Depending on abradant type and test specimen, the
            wheel surface may change (that is, become clogged) due to the
            pick up of coating or other materials from test specimens and
            must be cleaned at frequent intervals.
            4.5.2 The type of material being tested and the number of
            test cycles being run is known to sometimes inflfluence the
            temperature of the running surface of the wheel with an affect
            on the fifinal haze measurement. To reduce any variability due to
            this temperature effect, stabilize the wheels surface tempera
            ture prior to performing actual measurements. This shall be
            accomplished by conducting multiple refacings on an ST-11
            refacing stone, followed by a test on the sample material to be
            tested (with results to be discarded).


            5. Apparatus
            5.1 Abrader—The Taber abraser or its equivalent, consist
            ing of the following elements:
            5.1.1 A horizontal turntable platform; comprised of a rubber
            pad, clamp plate, and nut to secure the specimen to the
            turntable.
            5.1.2 A motor capable of rotating the turntable platform at a
            speed of either 72 6 2 r/min for 110v/60Hz or 60 6 2 r/min for
            230v/50Hz.
            5.1.3 A pair of pivoted arms, to which the abrasive wheels
            and auxiliary masses (if used) would be attached; loads of 500
            or 1000 gf on the wheels are obtained by use of changeable
            weights.
            NOTE 5—Without auxiliary masses or counterweights applied, each
            arm will apply a load against the specimen of 250 gf per wheel (exclusive
            of the mass of the wheel itself).
            5.1.4 A vacuum suction system and vacuum pick-up nozzle
            to remove debris and abrasive particles from the specimen
            surface during testing. The height of the vacuum pick-up
            nozzle shall be adjustable, and the nozzle openings shall be 11
            mm [716 in.] in diameter.
            NOTE 6—The nominal nozzle openings are 8 mm [516 in.] and can be
            enlarged following the instructions shown in Appendix X2.
            5.1.5 A counter to record the number of cycles (revolutions)
            made by the turntable platform.
            5.2 Refacing Stone—The fifine side of a ST-11 refacing stone
            (or equivalent) shall be used for refacing the abrasive wheels.
            It is important that the turntable platform runs true on the
            abraser and that the refacing stone lies flflat on the turntable
            platform.
            5.3 Abrasive Wheels—The grade of wheel designated CS-
            10F5 shall be used, and shall meet the following requirements
            at the time of the test:
            5.3.1 The wheel shall be 12.7 6 0.3 mm wide and have an
            external diameter of 51.9 6 0.5 mm when new, and in no case
            less than 44.4 mm, and
            5.3.2 The wheel shall not be used after the date stamped on
            it.
            5.4 Hazemeter—An integrating sphere photoelectric pho
            tometer, as described in Test Method D 1003, shall be used to
            measure the light scattered by the abraded track. If haze
            measurements are made with other devices or by other meth
            ods, a correlation shall be established with the results obtained
            with the apparatus and method described in Test Method
            D 1003.
            5.4.1 An aperture or diaphragm shall be centrally inserted in
            the haze measuring apparatus to center the light beam on the
            abraded track and limit it to a diameter of 7 6 1 mm [0.28 6
            0.04 in.] at the specimen.
            5.4.2 When the reduced light beam is unobstructed by a
            specimen, its cross section at the exit port shall be approxi
            mately circular, sharply defifined, uniformly bright, and concen
            tric within the exit port, leaving an annulus of 0.023 6 0.002
            rad (1.3 6 0.1°) subtended at the entrance port.
            5.5 Specimen Holder—A suitable holder shall be used to
            permit positioning the abraded specimen on the hazemeter so
            that the light beam is centered in the abraded track and the
            specimen is flflush at the measurement port.
            6. Test Specimens
            6.1 The test specimens shall be clean, transparent disks
            approximately 100 mm in diameter or plates approximately
            100 mm square, having both surfaces substantially plane and
            parallel. They may be cut from sheets or molded in thicknesses
            up to 12.7 mm [12 in.]. A 6.3-mm [14-in.] hole shall be
            centrally drilled in each specimen. Three such specimens shall
            be tested per sample, except for interlaboratory or specifification
            tests when ten specimens shall be tested.
            7. Calibration
            7.1 Verify calibration of the Taber abraser as directed by the
            equipment manufacturer (see Appendix X1).


            8. Conditioning
            8.1 Conditioning—Unless otherwise specifified, condition
            the test specimens at 23 6 2°C [73.4 6 3.6°F] and 50 6 5 %
            relative humidity for not less than 40 h prior to test in
            accordance with Procedure A of Practice D 618. In cases of
            disagreement, the tolerances shall be 61°C [61.8°F] and
            62 % relative humidity.
            8.2 Test Conditions—Conduct tests in the standard labora
            tory atmosphere of 23 6 2°C [73.4 6 3.6°F] and 50 6 5 %
            relative humidity, unless otherwise specifified. In cases of
            disagreements, the tolerances shall be 61°C [61.8°F] and
            62 % relative humidity.
            9. Standardization of Abrading Wheels
            9.1 To ensure that the abrading function of the wheels is
            maintained at a constant level, prepare the abrading wheels
            prior to each test.
            9.1.1 Mount the wheels on their respective flflange holders,
            taking care not to handle them by their abrasive surfaces.
            9.1.2 Select the load to be used and affix it to the abraser. If
            no load is specifified, use a load of 500 gf (per wheel).
            9.1.3 Mount an ST-11 refacing stone (or equivalent) on the
            turntable, fifine side up, and secure using the nut.
            9.1.4 Lower the vacuum nozzle and adjust its height to
            within 0.8 to 1.6 mm [132 to 116 in.] of the refacing stone. Set
            the vacuum suction force to 100.
            9.1.5 Lower the arms so the wheels contact the surface of
            the ST-11 refacing stone.
            9.2 Before abrading each specimen, reface the wheels for 25
            cycles on the fifine side of the ST-11 refacing stone. After
            refacing, use a soft bristle, anti-static brush to lightly brush the
            wheel surfaces to remove any loose particulate matter before
            abrading a specimen. (Warning—Do not touch the running
            surface of the wheels after they are refaced. New wheels or
            wheels trued using a diamond tool refacer, must fifirst be broken
            in with 100 cycles on the fifine side of the ST-11 refacing stone
            followed by a test on the material to be evaluated (results to be
            discarded).)
            NOTE 9—A brush found suitable for this purpose has been described as
            follows: Having a width of two inches with tuft spacing of 0.25 inches. It
            is a soft-fifiber, static-dissipative brush manufactured from an acrylic fifiber
            (0.0015 inch fifilament diameter) that has been chemically bonded with a
            layer of copper sulfifide to produce a resistance of 3–5 times 10-4 ohms per
            centimetre.
            NOTE 10—The fifine side of the ST-11 refacing stone has a limited life
            and must be replaced after 10,000 cycles (approximately 400 refacings).
            9.2.1 A thin fifin of wheel material will sometimes form on
            the left hand edge of the wheel as the main body of the wheel
            wears down. To remove, gently rub the edge of the wheel using
            your fifinger. Avoid touching the running surface of the wheel.
            9.2.2 The maximum allowed time between refacing and
            testing shall not exceed two minutes.
            10. Procedure
            10.1 Before testing, remove any protective masking mate
            rial from the specimen. If required, clean the specimen using a
            practice recommended by the manufacturer. Handle test pieces
            by their edges to prevent contamination of their surfaces.
            10.2 Place the unabraded specimen in the hazemeter sample
            holder with the side to be abraded facing the entrance port of
            the integrating sphere. Measure the haze percentage (initial
            haze) of the specimen at a minimum of four equally spaced
            points in the unabraded area. The results shall be averaged for
            each specimen.
            NOTE 11—As an operational qualifification step for the instrumental
            measurement of transmission haze, it is recommended to measure the haze
            percentage value with no sample present and verify that the reading of the
            hazemeter is 0. The sample holder must be removed during this measure
            ment.
            10.3 Mount the specimen on the abraser turntable platform
            with the side to be abraded facing up. Secure using the clamp
            plate and nut.
            10.4 Select the load to be used and affix it to the abraser.
            Lower the vacuum pick-up nozzle and adjust the height to
            within 0.8 to 1.6 mm [132 to 116 in.] of the specimen surface.
            Set the counter to zero and program the appropriate number of
            cycles. Start the abraser and subject the specimen to abrasion
            for a selected number of cycles. Use an abrasion of 100 cycles
            with the 500 load, unless otherwise specifified.
            remaining particulate. For those materials where IPA inflfluences
            the surface characteristics, use deionized water or a cleaning
            solution that is compatible with the sample.
            10.6 Place the abraded specimen in the hazemeter sample
            holder with the abraded track against the entrance port of the
            integrating sphere (facing away from the light source). Mea
            sure the haze percentage of the transmitted light that is diffused
            by the abraded track (fifinal haze) on at least four equally spaced
            intervals along the track. The results shall be averaged for each
            specimen. The specimen holder shall be positioned so that no
            portion of the light beam is within 1 mm of the inside or
            outside edge of the track.
            10.6.1 Percent haze, as defifined by Test Method D 1003, is
            calculated as follows:
            haze 5 [Td / Tt# 3 100 (1)
            where:
            Tt
            = total transmittance
            Td
            = diffuse transmittance
            NOTE 14—Subjective comparisons may be made by visually comparing
            abraded specimens with a measured, abraded standard.
            10.7 The initial haze percentage of the unabraded specimen
            determined by 10.2 shall be subtracted from the fifinal haze
            percentage of the abraded sample as measured by 10.6. The
            difference represents the light scatter resulting from abrading
            the specimen.
            11. Interpretation of Results
            11.1 The lower the percent haze difference, the more resis
            tant the specimen is to abrasive damage.
            12. Report
            12.1 Report the following information:
            12.1.1 Change in percentage of haze as calculated by 10.7,
            12.1.2 Number of specimens tested,
            12.1.3 Load and the number of cycles used, if other than
            specifified in 10.4,
            12.1.4 Wheel cleaning interval(s), if clogging is an issue,
            12.1.5 Temperature stabilization details (in accordance with
            4.5.2), if applicable,
            12.1.6 Cleaning solution used, if applicable,
            12.1.7 Rotational speed of turntable platform,
            12.1.8 Plot of the percentage of light scattered versus cycles
            abraded, if more than one number of cycles is used, and
            12.1.9 Description of the integrating sphere photometer
            including: sphere geometry; exit light beam diameter with and
            without the diaphragm inserted; and location of the diaphragm
            in the light beam. Alternatively, report the make and model of
            the hazemeter used.
            13. Precision and Bias
            13.1 Table 1 is based on a round robin conducted in 2004,
            involving fifive materials tested by fifive laboratories. Each lab
            made six (6) determinations for each material and cycle
            combination. It should be noted that the test procedure used for
            the round robin involved higher reface cycles, and no consid
            eration was given to the useful life of the ST-11 refacing stone.
            13.1.1 In Table 1 for the materials indicated:
            Sr = pooled within-laboratories standard deviation of the
            mean for three or ten specimens,
            SR = total among-laboratories standard deviation of the mean
            for three or ten specimens,
            r = 2.83 Sr (see 13.2), and
            R = 2.83 SR (see 13.3).
            Other materials may give somewhat different results.
            13.2 Repeatability—In comparing two averages for the
            same material, obtained by the same operator using the same
            equipment on the same day, the average should be judged not
            equivalent if they differ by more than the r value for that
            material and condition.
            13.3 Reproducibility—In comparing two averages for the
            same material, obtained by different operators using different
            equipment, the averages should be judged not equivalent if
            they differ by more than the R value for that material and
            condition.
            13.4 The judgments in accordance with 13.2 and
             

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